Functionalized bicyclo[3.3.0]octanes by enantioselective transannular desymmetrization.

Symplectic ID: 
31906
Source: 
PubMed
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1
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Monday, 14 September, 2026 - 14:42
DOI: 
10.1021/ol006947n
Publication Date: 
Thursday, 8 February, 2001
First Page: 
441
Last Page: 
444
Authors: 
Hodgson, DM
Cameron, ID
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0
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Abstract: 
[figure: see text] Enantioselective alpha-deprotonation-rearrangement of achiral substituted cyclooctene oxides 7, 17, and 18 using organolithiums in the presence of (-)-sparteine (3) or (-)-alpha-isosparteine (4) gives the functionalized bicyclo[3.3.0]octan-2-ols 8, 19, and 20 in 56-72% yields and 83-89% ee\'s.
ISSN: 
1523-7060
Journal Title: 
Org Lett
Volume: 
3
Issue: 
3
ID at Source: 
11428034
Publication Status: 
Published
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orie0168