Synthesis and the crystal structure of CeCuS2

Komatsuzaki S, Takase K, Smura CF, Takahashi Y, Takano Y, Sekizawa K, Clarke SJ

Single phase of CeCuS2 has been prepared by the mixture of CeO2 and Cu2S at 1000 ° C in CS2/Ar atmosphere. All X-ray diffraction peaks of CeCuS2 are indexed on the basis of the monoclinic system (space group: P21c) the same as LaCuS 2 and NdCuS2. The lattice parameters obtained by Rietveld analysis are a=0.6573(1) nm, b=0.7256(1) nm, c=0.6875(1) nm, and β=98.566(1)°. © 2005 Elsevier B.V. All rights reserved.